Chemical Formula

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To write the chemical formula of a compound, we must know the valency of the elements or polyatomic ions involved.

We can determine the valency from the group number in the periodic table.

In general, the normal valency of an atom is equal to the smaller of the following two numbers

• its periodic group number, or
• eight minus its group number.

Group Number in the Periodic Table	Example of element	Valency
I	Li, Na	1
II	Be, Mg	2
III	B, Al	3
IV	C, Si	4
V	N, P	3
VI	O, S	2
VII	F, Cl	1

Transition metallic elements have variable valencies. Their valencies are indicated by a Roman numeral in the bracket.

Example of transition metallic element	Valency
Copper (II)	2
Iron (III)	3
Lead (IV)	4
Manganese (VI)	6

There are radicals which consist of a group of atoms known as polyatomic ions. The following table shows the valencies of some common polyatomic ions.

Common polyatomic ions
Positive	Valency	Negative	Valency
Ammonium ion, NH4+	1	Nitrate ion, NO3-	1
		Hydroxide ion, OH-	1
		Carbonate ion, CO32-	2
		Sulphate ion, SO42-	2

Methods to deduce chemical formulas

1. Write the respective valency for each element and criss-cross.

2. If the valency is equal then just write out the formula.

3. If a number is required for polyatomic ions then a bracket must be used.

4. Reduce the ratio by a common factor if possible.

Formulas for Ionic Compounds
How to obtain the chemical formula for Aluminum Sulfide?

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How to obtain the chemical formula for Iron(III) Bromide?

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